A three stage model for adsorption of nonionic surfactants

Copyright @ 1993 American Institute of Physics.A three stage model for the adsorption of nonionic surfactants is proposed which makes use of existing theory from studies of random sequential adsorption. The model is simulated and the adsorption curves are found. The theory of random sequential adsorption is used to calculate the coverage exactly at the end of each of the three stages

DEVELOPMENT AND VALIDATION OF A PICTURE-PREFERENCE-TEST THOUGHT DISORDER SCALE.

Dept. of Psychology. Paper copy at Leddy Library: Theses & Major Papers - Basement, West Bldg. / Call Number: Thesis1979 .R939. Source: Dissertation Abstracts International, Volume: 40-04, Section: B, page: 1911. Thesis (Ph.D.)--University of Windsor (Canada), 1979

Spin-polarized transport through a single-level quantum dot in the Kondo regime

Nonequilibrium electronic transport through a quantum dot coupled to ferromagnetic leads (electrodes) is studied theoretically by the nonequilibrium Green function technique. The system is described by the Anderson model with arbitrary correlation parameter $U$. Exchange interaction between the dot and ferromagnetic electrodes is taken into account {\it via} an effective molecular field. The following situations are analyzed numerically: (i) the dot is symmetrically coupled to two ferromagnetic leads, (ii) one of the two ferromagnetic leads is half-metallic with almost total spin polarization of electron states at the Fermi level, and (iii) one of the two electrodes is nonmagnetic whereas the other one is ferromagnetic. Generally, the Kondo peak in the density of states (DOS) becomes spin-split when the total exchange field acting on the dot is nonzero. The spin-splitting of the Kondo peak in DOS leads to splitting and suppression of the corresponding zero bias anomaly in the differential conductance.Comment: 9 pages, 7 figure

Reversible adsorption on a random site surface

We examine the reversible adsorption of hard spheres on a random site surface in which the adsorption sites are uniformly and randomly distributed on a plane. Each site can be occupied by one solute provided that the nearest occupied site is at least one diameter away. We use a numerical method to obtain the adsorption isotherm, i.e. the number of adsorbed particles as a function of the bulk activity. The maximum coverage is obtained in the limit of infinite activity and is known exactly in the limits of low and high site density. An approximate theory for the adsorption isotherms, valid at low site density, is developed by using a cluster expansion of the grand canonical partition function. This requires as input the number of clusters of adsorption site of a given size. The theory is accurate for the entire range of activity as long as the site density is less than about 0.3 sites per particle area. We also discuss a connection between this model and the vertex cover problem.Comment: 16 pages, 10 figure

Characterization of polar organosulfates in secondary organic aerosol from the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal

We show in the present study that the unsaturated aldehydes 2-E-pentenal, 2-E-hexenal, and 3-Z-hexenal are biogenic volatile organic compound (BVOC) precursors for polar organosulfates with molecular weights (MWs) 230 and 214, which are also present in ambient fine aerosol from a forested site, i.e., K-puszta, Hungary. These results complement those obtained in a previous study showing that the green leaf aldehyde 3-Z-hexenal serves as a precursor for MW 226 organosulfates. Thus, in addition to isoprene, the green leaf volatiles (GLVs) 2-E-hexenal and 3-Z-hexenal, emitted due to plant stress (mechanical wounding or insect attack), and 2-E-pentenal, a photolysis product of 3-Z-hexenal, should be taken into account for secondary organic aerosol and organosulfate formation. Polar organosulfates are of climatic relevance because of their hydrophilic properties and cloud effects. Extensive use was made of organic mass spectrometry (MS) and detailed interpretation of MS data (i.e., ion trap MS and accurate mass measurements) to elucidate the chemical structures of the MW 230, 214 and 170 organosulfates formed from 2-E-pentenal and indirectly from 2-E-hexenal and 3-Z-hexenal. In addition, quantum chemical calculations were performed to explain the different mass spectral behavior of 2,3-dihydroxypentanoic acid sulfate derivatives, where only the isomer with the sulfate group at C-3 results in the loss of SO3. The MW 214 organosulfates formed from 2-E-pentenal are explained by epoxidation of the double bond in the gas phase and sulfation of the epoxy group with sulfuric acid in the particle phase through the same pathway as that proposed for 3-sulfooxy-2-hydroxy-2-methylpropanoic acid from the isoprene-related alpha,beta-unsaturated aldehyde methacrolein in previous work (Lin et al., 2013). The MW 230 organosulfates formed from 2-E-pentenal are tentatively explained by a novel pathway, which bears features of the latter pathway but introduces an additional hydroxyl group at the C-4 position. Evidence is also presented that the MW 214 positional isomer, 2-sulfooxy-3-hydroxypentanoic acid, is unstable and decarboxylates, giving rise to 1-sulfooxy-2-hydroxybutane, a MW 170 organosulfate. Furthermore, evidence is obtained that lactic acid sulfate is generated from 2-E-pentenal. This chemistry could be important on a regional and local scale where GLV emissions such as from grasses and cereal crops are substantial